Bifunctional Schiff base/Ti(IV) catalysts for  enantioselective  cyanoformylation of aldehydes with ethyl cyanoformate | Zendy

Ji Nan | Zendy; Yao Lin | Zendy; He Wei | Zendy; Li Yurong | Zendy

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Bifunctional Schiff base/Ti(IV) catalysts for enantioselective cyanoformylation of aldehydes with ethyl cyanoformate

Author(s) -

Ji Nan,

Yao Lin,

He Wei,

Li Yurong

Publication year - 2013

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.2951

Subject(s) - chemistry , bifunctional , enantioselective synthesis , cyanohydrin , schiff base , catalysis , enantiomeric excess , organic chemistry , bifunctional catalyst , enantiomer , polymer chemistry

A new bifunctional titanium/Schiff base catalyst was developed for the enantioselective cyanoformylation of aldehydes with ethyl cyanoformate. The reaction proceeded smoothly with a mild reaction condition to afford the cyanohydrin ethyl carbonates in high yields (up to 96%) and good enantioselectivities (up to 85% enantiomeric excess). Copyright © 2013 John Wiley & Sons, Ltd.

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