Synthesis of 2‐aminomethylpiperidine ruthenium(II) phosphine complexes and their applications in  transfer hydrogenation  of aryl ketones | Zendy

Türkmen Hayati | Zendy

Premium

Synthesis of 2‐aminomethylpiperidine ruthenium(II) phosphine complexes and their applications in transfer hydrogenation of aryl ketones

Author(s) -

Türkmen Hayati

Publication year - 2012

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.2924

Subject(s) - chemistry , phosphine , transfer hydrogenation , ruthenium , catalysis , aryl , medicinal chemistry , chelation , nuclear magnetic resonance spectroscopy , proton nmr , stereochemistry , organic chemistry , alkyl

The complex trans , cis ‐[RuCl 2 (PPh 3 ) 2 (ampi)] (2) was prepared by reaction of RuCl 2 (PPh 3 ) 3 with 2‐aminomethylpiperidine(ampi) (1). [RuCl 2 (PPh 2 (CH 2 ) n PPh 2 )(ampi) ( n = 3, 4, 5)] (3–5) were synthesized by displacement of two PPh 3 with chelating phosphine ligands. All complexes (2–5) were characterized by 1 H, 13 C, 31 P NMR, IR and UV‐visible spectroscopy and elemental analysis. They were found to be efficient catalysts for transfer hydrogen reactions. Copyright © 2012 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research