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Efficient pyridylbenzamidine ligands for palladium‐catalyzed Suzuki–Miyaura reaction
Author(s) -
Huang YingTang,
Tang Xiao,
Yang Yi,
Shen DongSheng,
Tan Cheng,
Liu FengShou
Publication year - 2012
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.2913
Subject(s) - chemistry , palladium , catalysis , aryl , ligand (biochemistry) , combinatorial chemistry , reaction conditions , organic chemistry , nitrogen , biochemistry , alkyl , receptor
A series of pyridylbenzamidine ligands were applied in palladium‐catalyzed Suzuki–Miyaura reactions and the effect of ligand on catalytic properties was evaluated. Under the optimization conditions, the bulky and electron‐donating nitrogen donor ligands were successfully used to catalyze the reaction of a variety of aryl bromides and aryl chlorides with arylboronic acid, giving the desired products in moderate to high yields. Copyright © 2012 John Wiley & Sons, Ltd.