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Nafion®‐supported oxovanadium‐catalyzed hydrophosphonylation of aldehydes under solventless conditions
Author(s) -
Weng ShiueShien,
Lin GuanYing,
Li HsinChun,
Yang KuoChen,
Yang TengMao,
Liu HuiChi,
Sie SyuanHua
Publication year - 2012
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.2879
Subject(s) - chemistry , catalysis , nafion , filtration (mathematics) , sulfonate , ion exchange resin , ion exchange , organic chemistry , nuclear chemistry , ion , electrochemistry , sodium , electrode , statistics , mathematics
A Nafion® resin‐supported oxovanadium(IV) catalyst was readily prepared via ion‐exchange method. This solid vanadyl perfluorinated sulfonate catalyst was used as an efficient and recoverable catalyst for the hydrophosphonylation of various aldehydes under solventless conditions at room temperature. The catalyst could be recovered by simple filtration and reused without a significant loss of activity. Copyright © 2012 John Wiley & Sons, Ltd.