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A comparative Suzuki reaction of aryl halides using a new dimeric orthopalladated complex under conventional and microwave irradiation conditions
Author(s) -
Hajipour Abdol R.,
Karami Kazem,
Tavakoli Ghazal
Publication year - 2012
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.2852
Subject(s) - chemistry , phenylboronic acid , catalysis , aryl , potassium carbonate , halide , phosphine , microwave irradiation , coupling reaction , aryl halide , suzuki reaction , solvent , polymer chemistry , organic chemistry , photochemistry , palladium , alkyl
The cross‐coupling reaction between phenylboronic acid and various types of aryl halides ( Suzuki reaction ) was carried out using a catalytic amount of a new phosphine‐based catalyst under microwave irradiation. The reaction conditions were optimized and results showed that, by application of this catalytic system, N ‐methyl‐2‐pyrrolidone as the solvent and potassium carbonate as the base, reactions could be completed in a short reaction time with high to excellent yields. Copyright © 2012 John Wiley & Sons, Ltd.