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Dinuclear Pd(II)–NHC complex derived from proline and its application toward Mizoroki–Heck reaction performed in water
Author(s) -
Ma MingTao,
Lu JianMei
Publication year - 2012
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.2833
Subject(s) - chemistry , heck reaction , carbene , catalysis , proline , aryl , acrylic acid , palladium , polymer chemistry , medicinal chemistry , organic chemistry , amino acid , polymer , monomer , biochemistry , alkyl
A novel dinuclear Pd(II)– N ‐heterocyclic carbene complex derived from proline was successfully synthesized and its structure was confirmed unambiguously by X‐ray single‐crystal diffraction. Furthermore, the complex was found to be a good catalyst in the Mizoroki–Heck reaction of aryl iodides and bromides with acrylic acid performed in pure water. Copyright © 2012 John Wiley & Sons, Ltd.