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AgOTf‐catalyzed transesterification of β ‐keto esters
Author(s) -
Das Rima,
Chakraborty Debashis
Publication year - 2012
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.2826
Subject(s) - transesterification , chemistry , yield (engineering) , catalysis , kinetics , organic chemistry , tertiary alcohols , primary (astronomy) , chemical kinetics , thermodynamics , quantum mechanics , astronomy , physics
AgOTf proved to be an effective catalyst for the transesterification of β ‐keto esters with primary, secondary and tertiary alcohols. The products were obtained in high yield within a reasonable reaction time period. The kinetics of the transesterification reaction were also studied and the reaction was found to follow second‐order kinetics. Copyright © 2012 John Wiley & Sons, Ltd.
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