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Syntheses and structures of Me 3 Sb + CH 2 COO − ·H 2 O, the monohydrate of the antimony analogue of betaine, and related compounds
Author(s) -
Balàzs Gàbor,
Balàzs Lucia,
Breunig Hans J.,
Lork Enno
Publication year - 2002
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.255
Subject(s) - chemistry , antimony , betaine , crystal structure , x ray crystallography , single crystal , crystallography , stereochemistry , inorganic chemistry , organic chemistry , diffraction , physics , optics
The syntheses of the antimony analogue of betaine, Me 3 Sb + CH 2 COO − (1), of the precursor [Me 3 SbCH 2 COOH][Br] (2) and of [Me 3 SbCH 2 COOCH 2 CH 3 ][Br] (3) are reported. A new method for the synthesis of solvent‐free Me 3 Sb is described. The structures of 1·H 2 O and 3 were determined by single crystal X‐ray diffractometry. Copyright © 2002 John Wiley & Sons, Ltd.