Silicon–oxygen‐bonded oligomers having thermoelectric switching properties | Zendy

Purkayastha Arup | Zendy; Baruah Jubaraj B. | Zendy

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Silicon–oxygen‐bonded oligomers having thermoelectric switching properties

Author(s) -

Purkayastha Arup,

Baruah Jubaraj B.

Publication year - 2001

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.214

Subject(s) - siloxane , chemistry , catalysis , tetramethylethylenediamine , polymer chemistry , palladium , thermoelectric effect , oxygen , organic chemistry , polymer , physics , thermodynamics

The electrical properties of siloxane oligomers prepared from the reaction of 1,4‐naphthalenediol or 1,4‐naphthoquinone with diphenylsilane using different palladium catalysts, such as PdCl 2 , Pd(TMEDA)Cl 2 , Pd(TEEDA)Cl 2 (where TMEDA = N , N ′‐tetramethylethylenediamine, TEEDA = N , N ′‐tetraethylethylenediamine), are dependent on the catalyst. Thermoelectric switching properties can be obtained from the siloxane prepared from the coupling reaction of diphenylsilane with 1,4‐naphthoquinone or 1,4‐naphthalenediol using Pd(TMEDA)Cl 2 as catalyst. Copyright © 2001 John Wiley & Sons, Ltd.

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