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Aluminiumorganic compounds of some metaldioximates
Author(s) -
Voiculescu Nicolae
Publication year - 2001
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.208
Subject(s) - chemistry , dimethylglyoxime , nickel , copper , substitution reaction , infrared spectroscopy , medicinal chemistry , inorganic chemistry , polymer chemistry , organic chemistry
Coordinated dioximes with nickel(II), palla‐dium(II) and copper(II) ions proved capable of giving substitution reactions with a series of aluminiumorganic compounds. Studies made on the reaction products have revealed that in the case of both dimethylglyoxime and diphenylglyoxime. The reaction products result from substitution of the OH…O hydrogen bridges existing in such compounds by OAlO bridges. All compounds reported in this paper were separated from the reaction mixture as coloured powders and were characterized by chemical analyses, IR spectroscopy, X‐ray diffraction spectra, proton NMR spectra and magnetic properties. Copyright © 2001 John Wiley & Sons, Ltd.