Use of mass spectroscopic techniques to elucidate the nature of the products of the oxidation of trimethylstibine in air | Zendy

Craig P. J. | Zendy; Forster S. A. | Zendy; Jenkins R. O. | Zendy; Lawson G. | Zendy; Miller D. | Zendy; Ostah N. | Zendy

Premium

Use of mass spectroscopic techniques to elucidate the nature of the products of the oxidation of trimethylstibine in air

Author(s) -

Craig P. J.,

Forster S. A.,

Jenkins R. O.,

Lawson G.,

Miller D.,

Ostah N.

Publication year - 2001

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.190

Subject(s) - chemistry , antimony , mass spectrometry , electrospray ionization , atmospheric pressure , oxygen , environmental chemistry , atmospheric pressure chemical ionization , oxide , atmospheric oxygen , chemical ionization , analytical chemistry (journal) , ion , electrospray , ambient pressure , ionization , organic chemistry , chromatography , thermodynamics , oceanography , geology , physics

In view of the biological production of trimethylstibine ((CH 3 ) 3 Sb) in the natural environment, the fate of this species when exposed to ambient oxygen has been studied. The results obtained show that the oxidation process leads to a complex series of products. Trimethylstibine oxide ((CH 3 ) 3 SbO) and a range of cyclic and linear oligomers have been detected using positive ion electrospray and atmospheric pressure chemical ionization techniques and the mass spectroscopic (MS) features are discussed. Dimethyl antimony ((CH 3 ) 2 Sb) species were not detected under the conditions used. The results from both MS techniques were similar. Copyright © 2001 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research