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Catalytic activity of cycloaurated complexes in the addition of 2‐methylfuran to methyl vinyl ketone
Author(s) -
Kilpin Kelly J.,
Jarman Bevan P.,
Henderson William,
Nicholson Brian K.
Publication year - 2011
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1842
Subject(s) - chemistry , methyl vinyl ketone , triphenylphosphine , selenide , ketone , catalysis , sulfide , methyl ketone , medicinal chemistry , organic chemistry , polymer chemistry , selenium
Cycloaurated gold(III) complexes derived from cycloaurated iminophosphorane, triphenylphosphine sulfide or selenide, or pyridylsulfonamide ligands have been assessed for their catalytic activity in the addition of 2‐methylfuran to methyl vinyl ketone. Addition of AgBF 4 was generally needed for high activity, although those with coordinated atoms of high trans influence showed some activity in the absence of added Ag + . Copyright © 2011 John Wiley & Sons, Ltd.