Bulk solvent‐free melt ring‐opening polymerization of  L ‐lactide catalyzed by Cu(II) and Cu(II)–Nd(III) complexes of the Salen‐type Schiff‐base ligand | Zendy

Chen LeiLei | Zendy; Ding LiQin | Zendy; Zeng Chu | Zendy; Long Yong | Zendy; Lü XingQiang | Zendy; Song JiRong | Zendy; Fan DaiDi | Zendy; Jin WenJuan | Zendy

Premium

Bulk solvent‐free melt ring‐opening polymerization of L ‐lactide catalyzed by Cu(II) and Cu(II)–Nd(III) complexes of the Salen‐type Schiff‐base ligand

Author(s) -

Chen LeiLei,

Ding LiQin,

Zeng Chu,

Long Yong,

Lü XingQiang,

Song JiRong,

Fan DaiDi,

Jin WenJuan

Publication year - 2011

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1760

Subject(s) - chemistry , bimetallic strip , schiff base , catalysis , polymer chemistry , polymerization , ligand (biochemistry) , lactide , solvent , ring opening polymerization , ring (chemistry) , medicinal chemistry , organic chemistry , polymer , biochemistry , receptor

A monometallic (Cu 2+ , 1) and a bimetallic (Cu 2+ Nd 3+ , 2) Salen‐type Schiff‐base complexes with different reactive species, could efficiently catalyze the bulk solvent‐free melt ring‐opening polymerization (ROP) of L ‐lactide. Especially for the bimetallic complex 2, the involvement of rare earth ion was important and influential to the catalytic behaviors. Copyright © 2011 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research