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Thermoregulated ligand–palladium‐catalyzed Suzuki reaction in water
Author(s) -
Liu Ning,
Liu Chun,
Yan Bo,
Jin Zilin
Publication year - 2011
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1736
Subject(s) - chemistry , palladium , catalysis , ligand (biochemistry) , suzuki reaction , combinatorial chemistry , organic chemistry , receptor , biochemistry
An efficient and recyclable protocol for the Suzuki reaction in water has been developed based on the cloud point of thermoregulated ligand Ph 2 P(CH 2 CH 2 O) n CH 3 ( n = 22). This method allows the preparation of a variety of biaryls in high yields and the catalytic system can be recycled four times with high efficiency. Copyright © 2010 John Wiley & Sons, Ltd.