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( Z )‐1,2‐bis(ethoxydimethylsilyl)arylethenes as new building blocks for organic synthesis
Author(s) -
Pawluc Piotr,
Hreczycho Grzegorz,
Szudkowska Justyna,
Franczyk Adrian,
Marciniec Bogdan
Publication year - 2010
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1699
Subject(s) - chemistry , electrophile , stereoselectivity , catalysis , ruthenium , reactivity (psychology) , organic synthesis , palladium , combinatorial chemistry , coupling (piping) , organic chemistry , medicine , mechanical engineering , alternative medicine , pathology , engineering
A new efficient synthetic protocol for highly stereoselective synthesis of ( Z )‐1,2‐bis(ethoxydimethylsilyl)arylethenes from vinylsilanes based on sequential ruthenium‐catalyzed silylative coupling‐palladium‐catalyzed Heck coupling is reported. Reactivity of title compounds towards carbon electrophiles in the catalytic desilylative arylation is discussed. Copyright © 2010 John Wiley & Sons, Ltd.