( Z )‐1,2‐bis(ethoxydimethylsilyl)arylethenes as new building blocks for organic synthesis | Zendy

Pawluc Piotr | Zendy; Hreczycho Grzegorz | Zendy; Szudkowska Justyna | Zendy; Franczyk Adrian | Zendy; Marciniec Bogdan | Zendy

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( Z )‐1,2‐bis(ethoxydimethylsilyl)arylethenes as new building blocks for organic synthesis

Author(s) -

Pawluc Piotr,

Hreczycho Grzegorz,

Szudkowska Justyna,

Franczyk Adrian,

Marciniec Bogdan

Publication year - 2010

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1699

Subject(s) - chemistry , electrophile , stereoselectivity , catalysis , ruthenium , reactivity (psychology) , organic synthesis , palladium , combinatorial chemistry , coupling (piping) , organic chemistry , medicine , mechanical engineering , alternative medicine , pathology , engineering

A new efficient synthetic protocol for highly stereoselective synthesis of ( Z )‐1,2‐bis(ethoxydimethylsilyl)arylethenes from vinylsilanes based on sequential ruthenium‐catalyzed silylative coupling‐palladium‐catalyzed Heck coupling is reported. Reactivity of title compounds towards carbon electrophiles in the catalytic desilylative arylation is discussed. Copyright © 2010 John Wiley & Sons, Ltd.

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