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Multiple receiver experiments for NMR spectroscopy of organosilicon compounds
Author(s) -
Kupče Ēriks,
Wrackmeyer Bernd
Publication year - 2010
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1692
Subject(s) - chemistry , organosilicon , analytical chemistry (journal) , nmr spectra database , spectral line , nuclear magnetic resonance spectroscopy , pulse sequence , two dimensional nuclear magnetic resonance spectroscopy , deuterium , spectroscopy , chemical shift , solvent , deuterium nmr , organic chemistry , stereochemistry , nuclear magnetic resonance , physics , quantum mechanics , astronomy
A new pulse sequence, 2D INEPT‐PANACEA, that allows parallel acquisition of 2D 29 Si 29 Si INADEQUATE and 2D 29 Si 1 H HMBC spectra and also provides the 1D 29 Si NMR spectrum has been designed for use with organosilicon compounds and tested using a mixture of OH‐terminated polydimethylsiloxanes. The spectra provide 29 SiO 29 Si connectivities and multiple bond 29 Si 1 H correlation spectra in a single measurement that can be recorded in as little time as 8 min. In addition, the 1D 29 Si NMR spectrum provides accurate measurement of 29 Si chemical shifts with a signal‐to‐noise ratio allowing for determination of 29 Si 13 C spin–spin coupling constants, and also serves as a frequency lock. The latter feature allows for recording of NMR spectra of neat liquid samples or of samples without a deuterated solvent. The second example of using multiple receivers involves PANSY‐COSY and PANSY‐TOCSY experiments, using silatrane glycol as a test sample. Copyright © 2010 John Wiley & Sons, Ltd.