A catalytic CC bond‐forming reaction between aliphatic fluorohydrocarbons and arylsilanes | Zendy

Lühmann Nicole | Zendy; Panisch Robin | Zendy; Müller Thomas | Zendy

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A catalytic CC bond‐forming reaction between aliphatic fluorohydrocarbons and arylsilanes

Author(s) -

Lühmann Nicole,

Panisch Robin,

Müller Thomas

Publication year - 2010

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1658

Subject(s) - chemistry , alkyl , catalysis , primary (astronomy) , polymer chemistry , combinatorial chemistry , medicinal chemistry , organic chemistry , physics , astronomy

CC coupling reactions between arylsilanes and alkylfluorides are efficiently catalyzed by disilyl cation 1. Primary as well as secondary alkylfluorides were quantitatively coupled with arylsilanes; however, in the case of tertiary fluorides, the hydrodefluorination reaction predominated. Primary alkylfluorides were found to give arenes with mostly rearranged alkyl substituents. In all cases subsequent Friedel–Crafts‐type chemistry occurred. Copyright © 2010 John Wiley & Sons, Ltd.

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