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Synthesis of poly(vinylene‐arsine)s‐stabilized silver nanoparticles
Author(s) -
Naka Kensuke,
Nakahashi Akiko,
Bravo Mia,
Chujo Yoshiki
Publication year - 2010
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1611
Subject(s) - arsine , chemistry , dimethylformamide , polymer chemistry , stabilizer (aeronautics) , nanoparticle , colloid , silver nanoparticle , organic chemistry , nanotechnology , catalysis , phosphine , materials science , mechanical engineering , solvent , engineering
Stabilization of poly(vinylene‐arsine)s (1) towards silver nanoparticles was carried out to estimate the coordination and protecting ability of phenyl‐substituted poly(vinylene‐arsine) (1a) and methyl‐substituted poly(vinylene‐arsine) (1b). In the presence of 1 in 1:1 ratio with AgNO 3 , colloidal solutions were obtained. The methyl‐substituted poly(vinylene‐arsine) (1b) is a better stabilizer for silver nanoparticles in N , N ‐dimethylformamide owing to its less bulky structure than the phenyl‐substituted poly(vinylene‐arsine) (1a). Copyright © 2010 John Wiley & Sons, Ltd.