Reduction of nitroarenes followed by propanol group transfer from tris(3‐hydroxypropyl)‐ amine and cyclization leading to quinolines under heterogeneous PdC catalysis | Zendy

Cho Chan Sik | Zendy; Kim Tae Gyun | Zendy; Yoon Nam Sik | Zendy

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Reduction of nitroarenes followed by propanol group transfer from tris(3‐hydroxypropyl)‐ amine and cyclization leading to quinolines under heterogeneous PdC catalysis

Author(s) -

Cho Chan Sik,

Kim Tae Gyun,

Yoon Nam Sik

Publication year - 2010

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1596

Subject(s) - chemistry , amine gas treating , catalysis , tris , medicinal chemistry , tin , chloride , polymer chemistry , organic chemistry , biochemistry

Nitroarenes having electron‐donating or ‐withdrawing substituents are reduced to anilines and cyclized with tris(3‐hydroxypropyl)amine in the presence of a catalytic amount of PdC along with tin(II) chloride and isopropanol in dioxane‐H 2 O medium to give the corresponding quinolines in good to excellent yields. Copyright © 2009 John Wiley & Sons, Ltd.

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