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Direct coupling reaction between alcohols and allyltrimethylsilane catalyzed by phosphomolybdic acid
Author(s) -
Kadam Santosh T.,
Lee Hanbin,
Kim Sung Soo
Publication year - 2010
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1527
Subject(s) - phosphomolybdic acid , chemistry , catalysis , yield (engineering) , nucleophile , alcohol , organic chemistry , coupling (piping) , coupling reaction , medicinal chemistry , mechanical engineering , materials science , engineering , metallurgy
Phosphomolybdic acid (PMA) is a simple and efficient catalyst for direct coupling reaction of alcohols with allyltrimethylsilane. Direct nucleophilic allylation of alcohol with allyltrimethylsilane proceeds in considerably good yield in the presence of catalytic amount of (0.5 mol %) PMA at room temperature. Copyright © 2009 John Wiley & Sons, Ltd.