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Cosolvent‐promoted electrophilic amination of organozinc reagents
Author(s) -
Daşkapan Tahir,
Yeşilbağ Ferhat,
Koca Selçuk
Publication year - 2009
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1498
Subject(s) - electrophilic amination , chemistry , reagent , amination , electrophile , combinatorial chemistry , organic chemistry , catalysis
In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high‐yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed. Copyright © 2009 John Wiley & Sons, Ltd.