Preparation of novel axially chiral NHC–Pd(II) complexes and their application in oxidative kinetic resolution of secondary alcohols | Zendy

Liu ShiJia | Zendy; Liu Lianjun | Zendy; Shi Min | Zendy

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Preparation of novel axially chiral NHC–Pd(II) complexes and their application in oxidative kinetic resolution of secondary alcohols

Author(s) -

Liu ShiJia,

Liu Lianjun,

Shi Min

Publication year - 2009

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1491

Subject(s) - chemistry , kinetic resolution , carbene , axial symmetry , catalysis , diamine , kinetic energy , medicinal chemistry , organic chemistry , polymer chemistry , stereochemistry , enantioselective synthesis , structural engineering , engineering , physics , quantum mechanics

Novel axially chiral N ‐heterocyclic carbene (NHC) Pd(II) complexes were prepared from optically active 1,1′‐binaphthalenyl‐2,2′‐diamine (BINAM) and H 8 ‐BINAM and their crystal structures were unambiguously determined by X‐ray diffraction. These chiral N ‐heterocyclic carbene (NHC) Pd(II) complexes were applied in the oxidative kinetic resolution of secondary alcohols using molecular oxygen as a terminal oxidant or under aerobic conditions, affording the corresponding sec ‐alcohols in good yields with moderate to good enantioselectivities. Copyright © 2009 John Wiley & Sons, Ltd.

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