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Hydrosilylation conditions applied on alkenyl benzylated xyloses: selective reduction and isomerization
Author(s) -
Hadad Caroline,
Bouquillon Sandrine,
Harakat Dominique,
Muzart Jacques
Publication year - 2009
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1487
Subject(s) - chemistry , isomerization , triethylsilane , hydrosilylation , moiety , double bond , catalysis , transition metal , selective reduction , medicinal chemistry , organic chemistry , photochemistry
In the presence of triethylsilane and different transition metal catalysts, the main reactive pathways observed from benzylated xyloses bearing an unsaturated tether were the reduction and the isomerization of the double bond without debenzylation of the sugar moiety. Copyright © 2009 John Wiley & Sons, Ltd.