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Synthesis, crystal structure and properties of a new lanthanide‐transition metal carbonyl cluster
Author(s) -
Ye Jiehui,
Su Haiquan,
Bai Fenghua,
Du Yong,
Zhang Yulong
Publication year - 2009
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1476
Subject(s) - chemistry , lanthanide , transition metal , metal carbonyl , carbon monoxide , cluster (spacecraft) , thermogravimetric analysis , catalysis , crystal structure , crystallography , carbonylation , single crystal , metal , inorganic chemistry , organic chemistry , ion , computer science , programming language
A new type heterobimetallic complex containing lanthanide and transition metal carbonyl cluster (LnM carbonyl cluster), Sm 2 {OOCCCo 3 (CO) 9 } 2 {OOCCF 3 } 4 {(CO) 9 Co 3 CCOOH} 4 , has been synthesized by reaction of (CO) 9 Co 3 CCOOH with Sm(OOCCF 3 ) 3 (H 2 O) 2 , and structurally characterized by single‐crystal X‐ray diffraction. Application of the complex as a catalyst precursor for hydrogenation of carbon monoxide (Fischer–Tropsch reaction) was explored, and the thermogravimetric behavior and magnetic properties of the compound were examined as well. Copyright © 2008 John Wiley & Sons, Ltd.