Synthesis, crystal structure and properties of a new lanthanide‐transition metal carbonyl cluster | Zendy

Ye Jiehui | Zendy; Su Haiquan | Zendy; Bai Fenghua | Zendy; Du Yong | Zendy; Zhang Yulong | Zendy

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Synthesis, crystal structure and properties of a new lanthanide‐transition metal carbonyl cluster

Author(s) -

Ye Jiehui,

Su Haiquan,

Bai Fenghua,

Du Yong,

Zhang Yulong

Publication year - 2009

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1476

Subject(s) - chemistry , lanthanide , transition metal , metal carbonyl , carbon monoxide , cluster (spacecraft) , thermogravimetric analysis , catalysis , crystal structure , crystallography , carbonylation , single crystal , metal , inorganic chemistry , organic chemistry , ion , computer science , programming language

A new type heterobimetallic complex containing lanthanide and transition metal carbonyl cluster (LnM carbonyl cluster), Sm 2 {OOCCCo 3 (CO) 9 } 2 {OOCCF 3 } 4 {(CO) 9 Co 3 CCOOH} 4 , has been synthesized by reaction of (CO) 9 Co 3 CCOOH with Sm(OOCCF 3 ) 3 (H 2 O) 2 , and structurally characterized by single‐crystal X‐ray diffraction. Application of the complex as a catalyst precursor for hydrogenation of carbon monoxide (Fischer–Tropsch reaction) was explored, and the thermogravimetric behavior and magnetic properties of the compound were examined as well. Copyright © 2008 John Wiley & Sons, Ltd.

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