Ruthenium  N ‐heterocyclic–carbene catalyzed diarylation of arene CH bond | Zendy

Yaşar Sedat | Zendy; Doǧan Öznur | Zendy; Özdemir Ismail | Zendy; Çetinkaya Bekir | Zendy

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Ruthenium N ‐heterocyclic–carbene catalyzed diarylation of arene CH bond

Author(s) -

Yaşar Sedat,

Doǧan Öznur,

Özdemir Ismail,

Çetinkaya Bekir

Publication year - 2008

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1392

Subject(s) - chemistry , carbene , catalysis , ruthenium , ring (chemistry) , aryl , medicinal chemistry , aromaticity , stereochemistry , organic chemistry , molecule , alkyl

Novel ruthenium‐1,3‐dialkylimidazolin‐2‐ylidene complexes ( 2a–e ) have been prepared and characterized by C, H, N analysis, 1 H‐NMR and 13 C‐NMR. The ortho position of the aromatic ring of pyridyl group substituted aromatic compound was directly arylated with aryl bromides and chlorides in the presence of a catalytic amount of [RuCl 2 (1,3‐dialkylimidazolin‐2‐ylidene)] complexes. Copyright © 2008 John Wiley & Sons, Ltd.

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