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Water‐soluble 2‐arylnaphthoxazole‐derived palladium (II) complexes as phosphine‐free catalysts for the Suzuki reaction in aqueous solvent
Author(s) -
Li Hong,
Wu Yangjie
Publication year - 2008
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1379
Subject(s) - chemistry , phenylboronic acid , phosphine , palladium , suzuki reaction , aryl , aqueous solution , catalysis , solvent , polymer chemistry , organic chemistry , alkyl
Two water‐soluble palladium (II) complexes 2 and 4 have been synthesized from easily available 2‐arylnaphthoxazole derivatives. They were successfully applied to the Suzuki coupling of aryl bromides with phenylboronic acid in water at 100 °C under phosphine‐free conditions. Copyright © 2008 John Wiley & Sons, Ltd.