Efficient homocoupling reactions of halide compounds catalyzed by manganese (II) chloride | Zendy

Yuan Yu | Zendy; Bian Yubo | Zendy

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Efficient homocoupling reactions of halide compounds catalyzed by manganese (II) chloride

Author(s) -

Yuan Yu,

Bian Yubo

Publication year - 2008

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1340

Subject(s) - chemistry , halide , manganese , catalysis , alkyl , magnesium , chloride , reaction conditions , carbon fibers , organic chemistry , combinatorial chemistry , polymer chemistry , materials science , composite number , composite material

A new efficient homocoupling reaction was reported in one pot by a combination of metallic magnesium and a catalytic amount of manganese (II) chloride. Various aromatic and alkyl halides underwent homocoupling smoothly, affording the corresponding symmetrical homocoupling compounds in moderate to good yields. The readily available MnCl 2 , the mild reaction conditions and the operational simplicity and practicability allow for an easy and practical procedure for the purpose of carboncarbon bond formation. Copyright © 2007 John Wiley & Sons, Ltd.

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