Cyanosilylation of carbonyl compounds catalyzed by sodium  L ‐histidine | Zendy

George Soney C. | Zendy; Kim Sung Soo | Zendy; Rajagopal Gurusamy | Zendy

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Cyanosilylation of carbonyl compounds catalyzed by sodium L ‐histidine

Author(s) -

George Soney C.,

Kim Sung Soo,

Rajagopal Gurusamy

Publication year - 2007

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1278

Subject(s) - chemistry , catalysis , yield (engineering) , histidine , salt (chemistry) , organic chemistry , sodium salt , combinatorial chemistry , inorganic chemistry , materials science , metallurgy , enzyme

An efficient protocol for the addition of trimethyl silanecarbonitrile to carbonyl compounds by employing 1 mol% of L ‐histidine sodium salt alone as the catalyst is presented. A variety of aromatic, aliphatic and cyclic carbonyl compounds have been converted into the corresponding trimethylethers in excellent yield (up to 99%) under mild conditions. Copyright © 2007 John Wiley & Sons, Ltd.

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