Tetrahydroquinoline and tetrahydroisoquinoline mixed ligand rhenium complexes with the SNS/S donor atom set | Zendy

Zablotskaya Alla | Zendy; Segal Izolda | Zendy; Lukevics Edmunds | Zendy; Belyakov Sergey | Zendy; Spies Hartmut | Zendy

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Tetrahydroquinoline and tetrahydroisoquinoline mixed ligand rhenium complexes with the SNS/S donor atom set

Author(s) -

Zablotskaya Alla,

Segal Izolda,

Lukevics Edmunds,

Belyakov Sergey,

Spies Hartmut

Publication year - 2007

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1201

Subject(s) - chemistry , denticity , rhenium , ligand (biochemistry) , methylene , tetrahydroisoquinoline , thiol , stereochemistry , crystallography , medicinal chemistry , crystal structure , inorganic chemistry , organic chemistry , biochemistry , receptor

New oxorhenium complexes with 3‐methylazapentane‐1,5‐dithiolate (SNMeS) and thiol functionalized monodentate tetrahydroquinolyl and tetrahydroisoquinolyl derivatives have been synthesized by simultaneous reaction of [PPh 3 ] 2 [Re(O)Cl 3 ] with tridentate HSNMeSH and the corresponding N‐heterocycle containing thiol. The characterization of complexes involved elemental analysis, IR, 1 H and 13 C NMR spectroscopy and X‐ray crystallographic analysis. The nature of the heterocycle in monodentate ligand, even situated at the distance of two methylene group length, has been found to have a significant influence on the molecular conformation. Metal complexes were found to be active in psychotropic in vivo and cytotoxicity in vitro screening. Copyright © 2007 John Wiley & Sons, Ltd.

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