Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids | Zendy

Ohlin C. André | Zendy; Béni Zolt´n | Zendy; Laurenczy G´bor | Zendy; Ruiz Nuria | Zendy; MasdeuBultó Anna M. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Heterogeneous dehalogenation of arylhalides in the presence of ionic liquids

Author(s) -

Ohlin C. André,

Béni Zolt´n,

Laurenczy G´bor,

Ruiz Nuria,

MasdeuBultó Anna M.

Publication year - 2007

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1194

Subject(s) - chemistry , ionic liquid , iodobenzene , halogenation , dehydrohalogenation , chlorobenzene , inorganic chemistry , formate , catalysis , bromobenzene , ionic bonding , ionic compound , organic chemistry , medicinal chemistry , ion

Dehydrohalogenation of haloaromatics in ionic liquids derived from ethylmethylimidazolium or similar salts has been performed using PdC, Pd(OAc) 2 and other catalysts using formate salts as a hydrogen source. In the ionic liquid [emim][BF 4 ], chlorobenzene was dehalogenated by up to 40%, bromobenzene up to 25% and iodobenzene up to 41% in 2 h. Reactions in the absence of the ionic liquid were also performed. Copyright © 2007 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research