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Two novel benzenedicarboxylate‐metal complexes: synthesis, crystal structures and fluorescent properties
Author(s) -
Song YiShan,
Yan Bing,
Chen ZhenXia
Publication year - 2007
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1187
Subject(s) - chemistry , fluorescence , crystal structure , ligand (biochemistry) , crystallography , metal , stereochemistry , hydrothermal synthesis , hydrothermal circulation , block (permutation group theory) , receptor , organic chemistry , geometry , mathematics , quantum mechanics , seismology , geology , biochemistry , physics
Two novel benzenedicarboxylate–metal complexes, [Sm(nphth)(Hnphth)(H 2 O) 3 • H 2 O] 2 and [Zn(nphth)(bipy)(H 2 O) •H 2 O] 2 (2) (H 2 nphth = 3‐nitrophthalic acid, bipy = 2,2′‐bipyridine), have been synthesized under hydrothermal condition and characterized by single‐crystal X‐ray diffraction. Both complex 1 and 2 exhibit a dimeric structure, and nphth ligand shows different coordination mode in the f‐block and d‐block complexes. The fluorescent properties of two complexes are investigated; the results reveal that the two complexes show different kinds of fluorescence. Copyright © 2007 John Wiley & Sons, Ltd.
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