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N , N , N ′, N ′, N ″‐Pentamethyl‐ N ″‐[(trifluorosilyl)methyl] phosphoric triamide. First example of the existence of intramolecular PO→Si coordination bond in the Si‐containing phosphoric triamides
Author(s) -
Lazareva Nataliya F.,
Albanov Alexander I.,
Lazarev Igor M.,
Pestunovich Vadim A.
Publication year - 2007
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1174
Subject(s) - chemistry , intramolecular force , medicinal chemistry , phosphoric acid , intramolecular reaction , stereochemistry , organic chemistry
The N , N , N ′, N ′, N ″‐pentamethyl‐ N ″‐(trifluorosilylmethyl)phosphoric triamide OP(NMe 2 ) 2 N(Me) CH 2 SiF 3 with intramolecular PO→Si coordination was formed by the reaction of N , N , N ′, N ′, N ″‐pentamethyl‐ N ″[(triethoxysilyl)methyl]phosphoric triamide with BF 3 ·Et 2 O. Copyright © 2007 John Wiley & Sons, Ltd.