Preparation and molecular structure of 2,6‐dimesitylphenyldichlorophosphane | Zendy

Overländer Claus | Zendy; Tirrée Jürgen J. | Zendy; Nieger Martin | Zendy; Niecke Edgar | Zendy; Moser Carmen | Zendy; Spirk Stefan | Zendy; Pietschnig Rudolf | Zendy

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Preparation and molecular structure of 2,6‐dimesitylphenyldichlorophosphane

Author(s) -

Overländer Claus,

Tirrée Jürgen J.,

Nieger Martin,

Niecke Edgar,

Moser Carmen,

Spirk Stefan,

Pietschnig Rudolf

Publication year - 2007

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1161

Subject(s) - chemistry , steric effects , chlorine atom , stereochemistry , bond length , position (finance) , atom (system on chip) , chlorine , crystallography , crystal structure , medicinal chemistry , organic chemistry , finance , computer science , economics , embedded system

Owing to steric congestion, the phosphane unit within the title compound is dislocated from the central position which is associated with a difference in the PCC angles of 20.3(2)° and a compression of the Cl bond distance of the chlorine atom involved in this repulsive interaction. Copyright © 2006 John Wiley & Sons, Ltd.

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