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Preparation and molecular structure of 2,6‐dimesitylphenyldichlorophosphane
Author(s) -
Overländer Claus,
Tirrée Jürgen J.,
Nieger Martin,
Niecke Edgar,
Moser Carmen,
Spirk Stefan,
Pietschnig Rudolf
Publication year - 2007
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1161
Subject(s) - chemistry , steric effects , chlorine atom , stereochemistry , bond length , position (finance) , atom (system on chip) , chlorine , crystallography , crystal structure , medicinal chemistry , organic chemistry , finance , computer science , economics , embedded system
Owing to steric congestion, the phosphane unit within the title compound is dislocated from the central position which is associated with a difference in the PCC angles of 20.3(2)° and a compression of the Cl bond distance of the chlorine atom involved in this repulsive interaction. Copyright © 2006 John Wiley & Sons, Ltd.