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Synthesis and properties study of novel ferrocenyl isoxazole derivatives
Author(s) -
Shang Yongjia,
Fan Chenli,
Li Maoguo,
Zheng Caiyun
Publication year - 2006
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1115
Subject(s) - isoxazole , chemistry , ferrocene , nitrile , cycloaddition , electrochemistry , 1,3 dipolar cycloaddition , crystal structure , single crystal , stereochemistry , combinatorial chemistry , polymer chemistry , medicinal chemistry , crystallography , organic chemistry , catalysis , electrode
A synthetic procedure based on the 1,3‐dipolar cycloaddition reactions of nitrile oxides and ethynylferrocene derived from ferrocene has been developed to synthesize new ferrocenyl‐isoxazole derivatives. The stable solids were thoroughly characterized by 1 H NMR, FT‐IR, and mass spectroscopy. The structure of (η 5 ‐C 5 H 5 ) Fe (η 5 ‐C 5 H 4 ) C 3 HNOC 6 H 4 CH 3 was determined by single‐crystal X‐ray diffraction. The electrochemical behaviors of the synthesized ferrocenyl‐isoxazole derivatives were also studied. Copyright © 2005 John Wiley & Sons, Ltd.