Synthesis and structures of cycloalkylidene‐bridged mixed cyclopentadienyl‐indenyl tetracarbonyl diruthenium complexes | Zendy

Lin Jin | Zendy; Luo Shuang | Zendy; Cheng Bin | Zendy; Wang Baiquan | Zendy; Xu Shansheng | Zendy; Song Haibin | Zendy

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Synthesis and structures of cycloalkylidene‐bridged mixed cyclopentadienyl‐indenyl tetracarbonyl diruthenium complexes

Author(s) -

Lin Jin,

Luo Shuang,

Cheng Bin,

Wang Baiquan,

Xu Shansheng,

Song Haibin

Publication year - 2006

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1067

Subject(s) - chemistry , cyclopentadienyl complex , medicinal chemistry , stereochemistry , catalysis , organic chemistry

A series of cycloalkylidene‐bridged mixed cyclopentadienyl‐indenyl tetracarbonyl diruthenium complexes (η 5 :η 5 ‐RC 5 H 3 CR′ 2 C 9 H 6 )Ru 2 (CO) 2 (µ‐CO) 2 [R = H, R′, R′ = Me 2 (1), (CH 2 ) 4 (2), (CH 2 ) 5 (3), (CH 2 ) 6 (4); R = t Bu, R′, R′ = Me 2 (5), (CH 2 ) 4 (6), (CH 2 ) 5 (7)] have been synthesized by reactions of the corresponding ligands RC 5 H 4 CR′ 2 C 9 H 7 with Ru 3 (CO) 12 in refluxing xylene. The molecular structures of 2, 6 and 7 have been determined by X‐ray diffraction. Copyright © 2006 John Wiley & Sons, Ltd.

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