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Synthesis and structures of cycloalkylidene‐bridged mixed cyclopentadienyl‐indenyl tetracarbonyl diruthenium complexes
Author(s) -
Lin Jin,
Luo Shuang,
Cheng Bin,
Wang Baiquan,
Xu Shansheng,
Song Haibin
Publication year - 2006
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1067
Subject(s) - chemistry , cyclopentadienyl complex , medicinal chemistry , stereochemistry , catalysis , organic chemistry
A series of cycloalkylidene‐bridged mixed cyclopentadienyl‐indenyl tetracarbonyl diruthenium complexes (η 5 :η 5 ‐RC 5 H 3 CR′ 2 C 9 H 6 )Ru 2 (CO) 2 (µ‐CO) 2 [R = H, R′, R′ = Me 2 (1), (CH 2 ) 4 (2), (CH 2 ) 5 (3), (CH 2 ) 6 (4); R = t Bu, R′, R′ = Me 2 (5), (CH 2 ) 4 (6), (CH 2 ) 5 (7)] have been synthesized by reactions of the corresponding ligands RC 5 H 4 CR′ 2 C 9 H 7 with Ru 3 (CO) 12 in refluxing xylene. The molecular structures of 2, 6 and 7 have been determined by X‐ray diffraction. Copyright © 2006 John Wiley & Sons, Ltd.