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Active ruthenium‐( N ‐heterocyclic carbene) complexes for hydrogenation of ketones
Author(s) -
Yiǧit Murat,
Yiǧit Beyhan,
Özdemir İsmail,
Çetinkaya Engin,
Çetinkaya Bekir
Publication year - 2006
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.1054
Subject(s) - chemistry , ruthenium , carbene , transfer hydrogenation , catalysis , noyori asymmetric hydrogenation , carbon 13 nmr , medicinal chemistry , organic chemistry , catalytic hydrogenation
Four ruthenium‐ N ‐heterocyclic carbene complexes ( 3–6 ) have been prepared and the new compounds characterized by C, H, N analyses, 1 H‐NMR and 13 C‐NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of complexes 3–6 in the presence of t ‐BuOK. Copyright © 2006 John Wiley & Sons, Ltd.
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