Hydrothermal synthesis of the fist two‐dimensional folded layer formed by a cyano‐bridged one‐dimensional chain joined by Cu(I)Cu(I) bonding | Zendy

Chen XiongBin | Zendy; Li YiZhi | Zendy; You XiaoZeng | Zendy

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Hydrothermal synthesis of the fist two‐dimensional folded layer formed by a cyano‐bridged one‐dimensional chain joined by Cu(I)Cu(I) bonding

Author(s) -

Chen XiongBin,

Li YiZhi,

You XiaoZeng

Publication year - 2006

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.1043

Subject(s) - chemistry , hydrothermal synthesis , hydrothermal circulation , crystallography , hydrothermal reaction , copper , chain (unit) , fist , stereochemistry , polymer , layer (electronics) , polymer chemistry , chemical engineering , organic chemistry , physiology , physics , astronomy , biology , engineering

Two cyano‐bridged polymers, [Cu 3 (CN) 3 (phen)] n ( 1 ) and [Cu(CN)(phen)] n ( 2 ) (phen = 1,10‐phenphralonine), were synthesized by the hydrothermal reaction of Cu(NO 3 ) 2 · 3H 2 O, K 3 [Fe(CN) 6 ] and phen and were characterized structurally by X‐ray, IR and ERSC methods. Compound 1 shows a two‐dimensional folded coordination network by Cu(I)CNCu(I) and Cu(I)Cu(I) interaction, while compound 2 exhibits an infinite helix chain by Cu(I)CN linkages. Copyright © 2005 John Wiley & Sons, Ltd.

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