Back Cover: Enzyme‐like Supramolecular Iridium Catalysis Enabling C−H Bond Borylation of Pyridines with  meta ‐Selectivity (Angew. Chem. Int. Ed. 33/2021) | Zendy

Trouvé Jonathan | Zendy; Zardi Paolo | Zendy; AlShehimy Shaymaa | Zendy; Roisnel Thierry | Zendy; GramageDoria Rafael | Zendy

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Back Cover: Enzyme‐like Supramolecular Iridium Catalysis Enabling C−H Bond Borylation of Pyridines with meta ‐Selectivity (Angew. Chem. Int. Ed. 33/2021)

Author(s) -

Trouvé Jonathan,

Zardi Paolo,

AlShehimy Shaymaa,

Roisnel Thierry,

GramageDoria Rafael

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202107624

Subject(s) - iridium , borylation , supramolecular chemistry , pyridine , catalysis , chemistry , selectivity , substrate (aquarium) , cover (algebra) , combinatorial chemistry , organic chemistry , molecule , biology , alkyl , aryl , mechanical engineering , ecology , engineering

Like an enzyme best describes the supramolecular catalyst reported by Rafael Gramage‐Doria et al. in their Research Article on page 18006. The remotely located Zn⋅⋅⋅N interactions within an iridium borylating catalyst are responsible for the unique selectivity and reactivity patterns observed for pyridine C−H bond functionalization. The pyridine approaches the substrate recognition pocket like a Perseid shooting star. Artwork: Romain Baloche.

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