Strained and Reactive Donor/Acceptor‐Supported Metallasilanone | Zendy

Takahashi Shintaro | Zendy; RamosEnríquez Manuel A. | Zendy; Bellan Ekaterina | Zendy; Baceiredo Antoine | Zendy; SaffonMerceron Nathalie | Zendy; Nakata Norio | Zendy; Hashizume Daisuke | Zendy; Branchadell Vicenç | Zendy; Kato Tsuyoshi | Zendy

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Strained and Reactive Donor/Acceptor‐Supported Metallasilanone

Author(s) -

Takahashi Shintaro,

RamosEnríquez Manuel A.,

Bellan Ekaterina,

Baceiredo Antoine,

SaffonMerceron Nathalie,

Nakata Norio,

Hashizume Daisuke,

Branchadell Vicenç,

Kato Tsuyoshi

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202105526

Subject(s) - acceptor , intramolecular force , reactivity (psychology) , molecule , ethylene , photochemistry , chemistry , materials science , stereochemistry , catalysis , organic chemistry , physics , medicine , alternative medicine , pathology , condensed matter physics

A novel stable donor/acceptor‐supported Mn I ‐metallasilanone 3 was synthesized. The intramolecular silanone‐Mn I interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 readily reacts with various small molecules such as H 2 or ethylene gas in mild conditions.

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