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Strained and Reactive Donor/Acceptor‐Supported Metallasilanone
Author(s) -
Takahashi Shintaro,
RamosEnríquez Manuel A.,
Bellan Ekaterina,
Baceiredo Antoine,
SaffonMerceron Nathalie,
Nakata Norio,
Hashizume Daisuke,
Branchadell Vicenç,
Kato Tsuyoshi
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202105526
Subject(s) - acceptor , intramolecular force , reactivity (psychology) , molecule , ethylene , photochemistry , chemistry , materials science , stereochemistry , catalysis , organic chemistry , physics , medicine , alternative medicine , pathology , condensed matter physics
A novel stable donor/acceptor‐supported Mn I ‐metallasilanone 3 was synthesized. The intramolecular silanone‐Mn I interaction induces a highly strained three‐membered cyclic structure, leading to an exceptionally high reactivity of 3 as a donor/acceptor complex of silanone. Indeed, metallasilanone 3 readily reacts with various small molecules such as H 2 or ethylene gas in mild conditions.