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Inside Back Cover: A Two‐Electron Silver Superatom Isolated from Thermally Induced Internal Redox Reaction of A Silver(I) Hydride (Angew. Chem. Int. Ed. 23/2021)
Author(s) -
Zhong YuJie,
Liao JianHong,
Chiu TzuHao,
Kahlal Samia,
Lin CheJen,
Saillard JeanYves,
Liu C. W.
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202104894
Subject(s) - nanoclusters , superatom , redox , cover (algebra) , cluster (spacecraft) , hydride , electron , materials science , nanotechnology , metal , chemistry , crystallography , physics , inorganic chemistry , organic chemistry , mechanical engineering , quantum mechanics , engineering , programming language , computer science
A new methodology was developed for the preparation of superatomic nanoclusters in a controllable fashion, with an internal redox reaction of Ag 7 (H)L 6 leading to the formation of a highly emissive two‐electron Ag nanocluster, Ag 10 L 8 . Jean‐Yves Saillard, Chen‐Wei Liu, and co‐workers explain in their Communication on page 12712 that the metal framework of Ag 7 is highly correlated to that of Ag 10 , suggesting that Ag 7 (H)L 6 acts as both reducing agent and template in the cluster build‐up.
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