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Inside Back Cover: Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral‐at‐Cluster Photoluminescence (Angew. Chem. Int. Ed. 19/2021)
Author(s) -
Horiuchi Shinnosuke,
Moon Sangjoon,
Ito Akitaka,
Tessarolo Jacopo,
Sakuda Eri,
Arikawa Yasuhiro,
Clever Guido H.,
Umakoshi Keisuke
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202102851
Subject(s) - cluster (spacecraft) , cover (algebra) , photoluminescence , enantiomer , core (optical fiber) , chemistry , center (category theory) , metal , crystallography , chirality (physics) , materials science , nanotechnology , stereochemistry , physics , chiral symmetry , optoelectronics , organic chemistry , computer science , composite material , nuclear physics , mechanical engineering , engineering , programming language , nambu–jona lasinio model , quark
Multinuclear precious metal sandwich complexes containing an asymmetric center in the cluster were synthesized as described by Shinnosuke Horiuchi, Keisuke Umakoshi, and co‐workers in the Research Article on page 10654. Reversible multipoint coordination in the cluster core can endow them with a remarkable stability, allowing separation of enantiomers and detection of chiroptical properties of the sandwich complexes in solution.