Dithienylethene‐Based Photochromic Siloles: A Straightforward and Divergent Synthetic Strategy

A straightforward synthetic methodology for the preparation of photochromic siloles based on the dithienylethene motif is developed. It relies upon an efficient palladium‐catalyzed annulation reaction of a 2,3‐bis(3‐thienyl)‐silirene with terminal alkynes in mild conditions. The reaction is functional group‐tolerant and can be performed in high yields with a variety of functional terminal alkynes. It can even be extended to a polymeric polypropargylmethacrylamide (PPMA) substrate affording the corresponding photochromic polymer with different degree of photochromic unit incorporation by simply adjusting the polymer/ silirene stoichiometric ratio.