Redefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*Co IV  Species | Zendy

LópezResano Sara | Zendy; Martínez de Salinas Sara | Zendy; GarcésPineda Felipe A. | Zendy; MoneoCorcuera Andrea | Zendy; GalánMascarós José Ramón | Zendy; Maseras Feliu | Zendy; PérezTemprano Mónica H. | Zendy

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Redefining the Mechanistic Scenario of Carbon−Sulfur Nucleophilic Coupling via High‐Valent Cp*Co IV Species

Author(s) -

LópezResano Sara,

Martínez de Salinas Sara,

GarcésPineda Felipe A.,

MoneoCorcuera Andrea,

GalánMascarós José Ramón,

Maseras Feliu,

PérezTemprano Mónica H.

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202101390

Subject(s) - nucleophile , chemistry , context (archaeology) , sulfur , surface modification , reductive elimination , coupling (piping) , catalysis , carbon fibers , combinatorial chemistry , stereochemistry , medicinal chemistry , organic chemistry , materials science , biology , paleontology , composite number , metallurgy , composite material

The potential access to Co IV species for promoting transformations that are particularly challenging at Co III still remains underexploited in the context of Cp*Co‐catalyzed C−H functionalization reactions. Herein, we disclose a combined experimental and computational strategy for uncovering the participation of Cp*Co IV species in a Cp*Co‐mediated C−S bond‐reductive elimination. These studies support the intermediacy of high‐valent Cp*Co species in C−H functionalization reactions, under oxidative conditions, when involving nucleophilic coupling partners.

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