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Pinning Effect Enhanced Structural Stability toward a Zero‐Strain Layered Cathode for Sodium‐Ion Batteries
Author(s) -
Chu Shiyong,
Zhang Chunchen,
Xu Hang,
Guo Shaohua,
Wang Peng,
Zhou Haoshen
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202100917
Subject(s) - cathode , materials science , electrochemistry , ion , structural stability , sodium , anode , slab , chemical engineering , chemical physics , electrode , chemistry , metallurgy , geophysics , geology , structural engineering , organic chemistry , engineering
Layered oxides as the cathode materials of sodium‐ion batteries are receiving extensive attention due to their high capacity and flexible composition. However, the layered cathode tends to be thermodynamically and electrochemically unstable during (de)sodiation. Herein, we propose the pinning effect and controllable pinning point in sodium storage layered cathodes to enhance the structural stability and achieve optimal electrochemical performance. 0 %, 2.5 % and 7.3 % transition‐metal occupancies in Na‐site as pinning points are obtained in Na 0.67 Mn 0.5 Co 0.5− x Fe x O 2 . 2.5 % Na‐site pinned by Fe 3+ is beneficial to restrain the potential slab sliding and enhance the structural stability, resulting in an ultra‐low volume variation of 0.6 % and maintaining the smooth two‐dimensional channel for Na‐ion transfer. The Na 0.67 Mn 0.5 Co 0.4 Fe 0.1 O 2 cathode with the optimal Fe 3+ pinning delivers outstanding cycle performance of over 1000 cycles and superior rate capability up to 10 C.