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π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons
Author(s) -
MartínezAbadía Marta,
Strutyński Karol,
LermaBerlanga Belén,
Stoppiello Craig T.,
Khlobystov Andrei N.,
MartíGastaldo Carlos,
Saeki Akinori,
MelleFranco Manuel,
MateoAlonso Aurelio
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202100434
Subject(s) - stacking , covalent bond , covalent organic framework , aromaticity , chemistry , topology (electrical circuits) , materials science , organic chemistry , molecule , engineering , electrical engineering
Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic ( D 3 d ) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs.