Frontispiece: Counter‐Intuitive Gas‐Phase Reactivities of [V 2 ] +  and [V 2 O] +  towards CO 2  Reduction: Insight from Electronic Structure Calculations | Zendy

Li Jilai | Zendy; Geng Caiyun | Zendy; Weiske Thomas | Zendy; Schwarz Helmut | Zendy

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Frontispiece: Counter‐Intuitive Gas‐Phase Reactivities of [V 2 ] + and [V 2 O] + towards CO 2 Reduction: Insight from Electronic Structure Calculations

Author(s) -

Li Jilai,

Geng Caiyun,

Weiske Thomas,

Schwarz Helmut

Publication year - 2020

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202083061

Subject(s) - gas phase , counterintuitive , chemistry , electronic structure , oxygen atom , atom (system on chip) , oxygen , atomic physics , physics , computational chemistry , quantum mechanics , molecule , computer science , organic chemistry , embedded system

Gas‐Phase Chemistry The fleeting existence of [V 2 O] + as a reactive intermediate in the oxidation of [V 2 ] + by CO 2 is described by J. Li, H. Schwarz et al. in their Communication on page 12308. The counterintuitive oxidation behavior of [V 2 ] + can be traced back to the supportive role of the bridging oxygen atom in [V 2 O] + .

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