Premium
Frontispiece: Diastereoselective Synthesis of P‐Chirogenic and Atropisomeric 2,2′‐Bisphosphino‐1,1′‐binaphthyls Enabled by Internal Phosphine Oxide Directing Groups
Author(s) -
Xue Qingquan,
Huo Shangfei,
Wang Tingyi,
Wang Zeming,
Li Jianli,
Zhu Meifang,
Zuo Weiwei
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202082162
Subject(s) - ligand (biochemistry) , phosphine , phosphine oxide , asymmetric hydrogenation , ruthenium , chemistry , catalysis , enantioselective synthesis , organic chemistry , receptor , biochemistry
Asymmetric Hydrogenation In their Research Article on page 8153, M. Zhu, W. Zuo et al. report a chiral diphosphine ligand that is both atropoisomeric and P‐chirogenic. A ruthenium–ligand catalyst exhibits good enantioselectivity in the asymmetric hydrogenation of 3‐methyl‐2‐butanone.