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Frontispiece: Enantioselective Total Synthesis and Absolute Configuration Assignment of (+)‐Tronocarpine Enabled by an Asymmetric Michael/Aldol Reaction
Author(s) -
Tan DongXing,
Zhou Jie,
Liu ChaoYou,
Han FuShe
Publication year - 2020
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202081061
Subject(s) - enantioselective synthesis , absolute configuration , total synthesis , aldol reaction , michael reaction , natural product , core (optical fiber) , stereochemistry , absolute (philosophy) , chemistry , computer science , organic chemistry , catalysis , philosophy , telecommunications , theology
Natural Product Synthesis In their Communication on page 3834, F.‐S. Han et al. report the asymmetric total synthesis and absolute configuration determination of (+)‐tronocarpine. The [6.5.7.6.6] pentacyclic core was constructed by using a sequential cyclization strategy.