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Zn‐Cu‐In‐S‐Se Quinary “Green” Alloyed Quantum‐Dot‐Sensitized Solar Cells with a Certified Efficiency of 14.4 %
Author(s) -
Song Han,
Lin Yu,
Zhou Mengsi,
Rao Huashang,
Pan Zhenxiao,
Zhong Xinhua
Publication year - 2021
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.202014723
Subject(s) - quinary , quantum dot , materials science , optoelectronics , ion , energy conversion efficiency , metallurgy , alloy , chemistry , organic chemistry
The photoelectronic properties of quantum dots (QDs) have a critical impact on the performance of quantum‐dot‐sensitized solar cells (QDSCs). Currently, I‐III‐VI group QDs have become the mainstream light‐harvesting materials in high‐performance QDSCs. However, it is still a great challenge to achieve satisfactory efficiency for light‐harvesting, charge extraction, and charge collection simultaneously in QDSCs. We design and prepare Zn 0.4 Cu 0.7 In 1.0 S x Se 2− x (ZCISSe) quinary alloyed QDs by cation/anion co‐alloying strategy. The critical photoelectronic properties of target QDs, including band gap, conduction band energy level, and density of defect trap states, can be conveniently tailored. Experimental results demonstrate that the ZCISSe quinary alloyed QDs can achieve an ideal balance among light‐harvesting, photogenerated electron extraction, and charge‐collection efficiencies in QDSCs compared to its single anion or cation quaternary alloyed QD counterparts. Consequently, the quinary alloyed QDs boost the certified efficiency of QDSCs to 14.4 %, which is a new efficiency record for liquid‐junction QD solar cells.