Reduction and Rearrangement of a Boron(I) Carbonyl Complex | Zendy

Rang Maximilian | Zendy; Fantuzzi Felipe | Zendy; Arrowsmith Merle | Zendy; Krummenacher Ivo | Zendy; Beck Eva | Zendy; Witte Robert | Zendy; Matler Alexander | Zendy; Rempel Anna | Zendy; Bischof Tobias | Zendy; Radacki Krzysztof | Zendy; Engels Bernd | Zendy; Braunschweig Holger | Zendy

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Reduction and Rearrangement of a Boron(I) Carbonyl Complex

Author(s) -

Rang Maximilian,

Fantuzzi Felipe,

Arrowsmith Merle,

Krummenacher Ivo,

Beck Eva,

Witte Robert,

Matler Alexander,

Rempel Anna,

Bischof Tobias,

Radacki Krzysztof,

Engels Bernd,

Braunschweig Holger

Publication year - 2021

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.202014167

Subject(s) - reduction (mathematics) , boron , chemistry , mathematics , organic chemistry , geometry

The one‐electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)‐stabilized arylborylene carbonyl complex yields a dimeric borylketyl radical anion, resulting from an intramolecular aryl migration to the CO carbon atom. Computational analyses support the existence of a [(CAAC)B(CO)Ar] .− radical anion intermediate. Further reduction leads to a highly nucleophilic dianionic (boraneylidene)methanolate.

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